Problem 11.3: For each case identify the primary pillar and
From Chapter 11 Problem Set. Level 1: Conceptual Mastery.
Question
For each case, identify the primary pillar and the most likely amplifier:
- Deep pitting beneath brown tubercles on mild steel
- White mineral deposit on a warm tube with soft slime beneath it
- Rapid oxidant demand increase after weeks of poor filtration
- Stable bulk chemistry but increasing condenser approach temperature
Answer
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These cases allow for some interpretation, but strong answers will generally follow this logic:
- Primary: corrosion. Amplifier: solids/deposit formation. The deposit creates the oxygen differential and helps localize attack.
- Primary: scale. Amplifier: biology. The mineral deposit is the dominant feature, but biofilm likely contributed by insulating the surface and trapping ions.
- Primary: biology. Amplifier: solids. Poor solids control creates shelter and surface area for biological growth, increasing oxidant demand.
- Primary: scale or solids. Amplifier: biology, if biofilm is part of the insulating layer. The key insight is that the problem is likely at the surface rather than in the bulk water.